CATALYTIC-OXIDATION OF TOXIC ORGANICS IN SUPERCRITICAL WATER

Authors
Citation
M. Krajnc et J. Levec, CATALYTIC-OXIDATION OF TOXIC ORGANICS IN SUPERCRITICAL WATER, Applied catalysis. B, Environmental, 3(2-3), 1994, pp. 120000101-120000107
Citations number
9
Categorie Soggetti
Chemistry Physical","Engineering, Environmental
ISSN journal
09263373
Volume
3
Issue
2-3
Year of publication
1994
Pages
120000101 - 120000107
Database
ISI
SICI code
0926-3373(1994)3:2-3<120000101:COTOIS>2.0.ZU;2-7
Abstract
Oxidation of some toxic organic compounds in supercritical water is in vestigated in the presence of a solid catalyst in an isothermal plug f low fixed-bed reactor. Comparison between catalyzed and noncatalyzed o xidations indicates that the conversions are much higher when the cata lyst is present. It is also found that the heterogeneous oxidation rou te forms less intermediate products during the decomposition of organi cs such as benzoic acid and 1-methyl-2-pyrrolidone in carbon dioxide.