INTERACTION OF 1,6-ANHYDRO DERIVATIVES OF AMINO-SUGARS WITH COPPER(II) IONS .2.

Authors
JEZOWSKABOJCZUK M KOZLOWSKI H TRNKA T CERNY M
Citation
M. Jezowskabojczuk et al., INTERACTION OF 1,6-ANHYDRO DERIVATIVES OF AMINO-SUGARS WITH COPPER(II) IONS .2., Carbohydrate research, 253, 1994, pp. 19-28
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Carbohydrate research → ACNP
ISSN journal
00086215
Volume
253
Year of publication
1994
Pages
19 - 28
Database
ISI
SICI code
0008-6215(1994)253:<19:IO1DOA>2.0.ZU;2-T
Abstract
The synthesis of ,6-anhydro-2-deoxy-4-O-methyl-beta-D-mannopyranose (3 ) is described. Potentiometric and spectroscopic methods were used to evaluate the equilibria and the complex structures in systems containi ng Cu(II) ions and 3, and two other 1,6-anhydro derivatives. The resul ts showed that no mannosamine derivative is able to form dimeric speci es found earlier for 1,6-anhydro-glucosamine ligands. The correlation between complex formation and sugar structure is discussed.