W. Ahmed et al., ISOLATION AND CHARACTERIZATION OF SAPONINS FROM CASTANOSPERMUM-AUSTRALE CUNN ET FRASER, Chemical and Pharmaceutical Bulletin, 42(2), 1994, pp. 314-317
Three new triterpenoid saponins, their methyl esters designated as cas
taralesides F (1), G (2) and H (3), were isolated from the fresh leave
s of Castanospermum australe. The structures of these three saponins w
ere elucidated on the basis of chemical and spectral data as 3 beta-O-
[beta-galactopyranosyl-(1 --> 4)-beta-glucuronopyranosyl]-2 beta,23-di
hydroxyolean-1 2-en-28-oic acid; 3 beta-O-[alpha-rhamnopyranosyl-(1 --
> 4)-beta-galactopyranosyl-(1 --> 2)-beta-glucuronopyranosyl]-2 beta,2
8-dihydroxyolean-12-ene; and 3 beta-O-[alpha-rhamnopyranosyl-(1 --> 4)
-beta-xylopyranosyl-(1 --> 2)-beta-glucuronopyranosyl]-2 beta,28-dihyd
roxyolean-12-ene.