A comprehensive experimental dataset was used to analyse the compositi
onal dependence of the garnet-clinopyroxene Fe2+/Mg partition coeffici
ent (K(d)). The Mg no. of garnet was found to have a significant effec
t on the K(d), in addition to calcium content of garnet. An empirical
model was developed to relate these effects with equilibrium temperatu
re and pressure in the form of a conventional geothermometer, T(K) = {
-1629[X(Ca)Gt]2 + 3648.55[X(Ca)Gt] -6.59[Mg no. (Gt)] + 1987.98 + 17.6
6P(kbar)}/(ln K(d) + 1.076). Application of this thermometer produced
reasonable temperature estimates for rocks from the lower crust (garne
t amphibolites, granulites and eclogites) and the upper mantle (eclogi
te and lherzolite xenoliths in kimberlites, mineral inclusions in diam
onds).