CATALYSIS OF ALLYLIC SUBSTITUTIONS BY PD COMPLEXES OF OXAZOLINES CONTAINING AN ADDITIONAL P, S, OR SE CENTER - X-RAY CRYSTAL-STRUCTURES ANDSOLUTION STRUCTURES OF CHIRAL PI-ALLYL PALLADIUM COMPLEXES OF PHOSPHINOARYLOXAZOLINES

Authors
SPRINZ J KIEFER M HELMCHEN G HUTTNER G WALTER O ZSOLNAI L REGGELIN M
Citation
J. Sprinz et al., CATALYSIS OF ALLYLIC SUBSTITUTIONS BY PD COMPLEXES OF OXAZOLINES CONTAINING AN ADDITIONAL P, S, OR SE CENTER - X-RAY CRYSTAL-STRUCTURES ANDSOLUTION STRUCTURES OF CHIRAL PI-ALLYL PALLADIUM COMPLEXES OF PHOSPHINOARYLOXAZOLINES, Tetrahedron letters, 35(10), 1994, pp. 1523-1526
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
10
Year of publication
1994
Pages
1523 - 1526
Database
ISI
SICI code
0040-4039(1994)35:10<1523:COASBP>2.0.ZU;2-H
Abstract
Allylic alkylations with Pd complexes of chiral oxazolines with an add itional donor P, S, or Se center are reported. Crystal and solution st ructures of palladium pi-allyl complexes of phosphinoaryloxazolines we re determined by X-ray crystallography and cross relaxation experiment s, respectively. From the results conclusions concerning the steric co urse of allylic substitutions are drawn.