STEREOSELECTIVE SYNTHESIS OF (E)-VINYLSILANE AND (Z)-VINYLSILANE BY THE ADDITION-REACTION OF ORGANOMETALLIC REAGENT TO SILYL-SUBSTITUTED FISCHER-TYPE CARBENE COMPLEX

Authors
IWASAWA N SAITOU M
Citation
N. Iwasawa et M. Saitou, STEREOSELECTIVE SYNTHESIS OF (E)-VINYLSILANE AND (Z)-VINYLSILANE BY THE ADDITION-REACTION OF ORGANOMETALLIC REAGENT TO SILYL-SUBSTITUTED FISCHER-TYPE CARBENE COMPLEX, Chemistry Letters, (2), 1994, pp. 231-234
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1994
Pages
231 - 234
Database
ISI
SICI code
0366-7022(1994):2<231:SSO(A(>2.0.ZU;2-M
Abstract
The addition reaction of Organolithium or Grignard reagents to pentaca rbonyl[methoxy(methyldiphenylsilyl) carbene]molybdenum is examined, an d either (E)- or (Z)-vinylsilanes are obtained with high selectivities depending on the reaction conditions.