SYNTHESIS AND PROPERTIES OF GERMYLENE-BRIDGED DIIRON COMPLEXES USING T-BUTYLGERMANE AS A PRECURSOR OF LIGANDS

Authors
KAWANO Y SUGAWARA K TOBITA H OGINO H
Citation
Y. Kawano et al., SYNTHESIS AND PROPERTIES OF GERMYLENE-BRIDGED DIIRON COMPLEXES USING T-BUTYLGERMANE AS A PRECURSOR OF LIGANDS, Chemistry Letters, (2), 1994, pp. 293-296
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
2
Year of publication
1994
Pages
293 - 296
Database
ISI
SICI code
0366-7022(1994):2<293:SAPOGD>2.0.ZU;2-6
Abstract
Photolysis of CpFe(CO)(2)SiMe(3) (Cp = eta-C5H5) in the presence of a new alkylgermane (t)BuGeH(3) afforded a mono(mu-germylene)diiron compl ex Cp(2)Fe(2)(CO)3(mu- GeH(t)Bu) (4) and a bis(mu-germylene)diiron com plex Cp(2)Fe(2)(CO)(2)(mu-GeH(t)Bu)(2) (5). The structure of 4 was det ermined by X-ray crystallography.