K. Lafdi et A. Oberlin, AN ATTEMPT TO CHARACTERIZE AND ELABORATE ANISOTROPIC PITCHES AND DERIVED CARBON-FIBERS .2. PREPARATION BY SEPARATION, Carbon, 32(1), 1994, pp. 61-70
Separation process yields anisotropic pitches without orientated aniso
tropic droplets. Laboratory and industrial pitches (D1, D2, E1, and E2
) were characterized and compared to two experimental pitches. The lat
ter were obtained by fractionation of the two component pitches B3 and
C by toluene. After graphitization, the fibers issued from these pitc
hes are entirely devoided of zig-zag. However they are rich in disclin
ations distributed at random. The amount of final disclinations largel
y overcome the amount already present in the initial pitch. The physic
ochemical properties of these pitches, their preparation procedure, th
e textures at various scales of the derived fibers, and their graphiti
zability as well as compared to those studied in part 1.