C. Morawe et al., EPITAXIAL-GROWTH OF CO CU [100] AND [111] SUPERLATTICES VIA RF-SPUTTERING ON SAPPHIRE (11(2)OVER-BAR0)-SUBSTRATES/, Journal of materials research, 9(3), 1994, pp. 570-581
Co/Cu superlattices with total thicknesses ranging from 10 nm to 60 nm
and with periodicities of 1.6-8.5 nm were sputtered on single-crystal
line sapphire (1120BAR)-substrates. Sputtering with low rates at room
temperature yields samples of high epitaxial and crystalline quality.
By careful choice of the sputtering parameters, either the fcc [100] o
r the fcc [111] orientation can be selected as growth direction on one
and the same substrate orientation. The preference for a particular f
ilm orientation appears to be kinetically driven. In all cases, the av
erage lattice spacings dBAR and the appearance of satellite reflection
s in x-ray Bragg-scans point to coherent growth up to thicknesses of 3
0 nm. X-ray small angle reflectivity measurements reveal clear oscilla
tions and satellites indicative for smooth interfaces. Scanning electr
on microscope (SEM) and transmission electron microscope (TEM) observa
tions supplement the characterization of the films.