CYCLOADDITION VS CONJUGATIVE MICHAEL-TYPE ADDITION OF 2-ETHOXY-3-MORPHOLINOBUTA-1,3-DIENE WITH NITROOLEFINS

Citation
G. Marc et al., CYCLOADDITION VS CONJUGATIVE MICHAEL-TYPE ADDITION OF 2-ETHOXY-3-MORPHOLINOBUTA-1,3-DIENE WITH NITROOLEFINS, Journal of the Chemical Society. Perkin transactions. I, (3), 1997, pp. 223-228
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
0300922X
Issue
3
Year of publication
1997
Pages
223 - 228
Database
ISI
SICI code
0300-922X(1997):3<223:CVCMAO>2.0.ZU;2-L
Abstract
The reactivity of the title dienamine towards conjugated nitroolefins has been investigated. With 1-nitrocyclopentene carbocyclic products l argely predominated, whereas with 1-nitrocyclohexene only Michael-type products were formed, The behaviour of beta-nitrostyrene was found to be dependent on the reaction conditions used.