HIGH-RESOLUTION PHOTOACOUSTIC OVERTONE SPECTRUM OF MONOCHLOROACETYLENE USING A TITANIUM-SAPPHIRE RING LASER SPECTROMETER

Authors
SAARINEN M HALONEN L POLANZ O
Citation
M. Saarinen et al., HIGH-RESOLUTION PHOTOACOUSTIC OVERTONE SPECTRUM OF MONOCHLOROACETYLENE USING A TITANIUM-SAPPHIRE RING LASER SPECTROMETER, Chemical physics letters, 219(3-4), 1994, pp. 181-186
Citations number
36
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
219
Issue
3-4
Year of publication
1994
Pages
181 - 186
Database
ISI
SICI code
0009-2614(1994)219:3-4<181:HPOSOM>2.0.ZU;2-I
Abstract
The photoacoustic overtone spectrum of monochloroacetylene (monochloro ethyne, HCCCl) has been recorded in the wave-number region 9500-14400 cm-1 with a titanium: sapphire ring laser. The spectrum shows several vibration-rotation band systems of which 3nu1 + nu2 and 4nu1 have been recorded with Doppler-limited resolution. Many overtone and hot bands belonging to Cl-35 and Cl-37 species have been analyzed rotationally. Some of the observed bands show rotational perturbations. Two of thes e bands have successfully been interpreted as a Fermi resonance pair.