FEASIBILITY STUDY OF RAMAN-SPECTROSCOPY AS A TOOL TO INVESTIGATE THE LIQUID-PHASE CHEMISTRY OF ALIPHATIC ORGANIC PEROXIDES

Authors
JACOB P WEHLING B HILL W KLOCKOW D
Citation
P. Jacob et al., FEASIBILITY STUDY OF RAMAN-SPECTROSCOPY AS A TOOL TO INVESTIGATE THE LIQUID-PHASE CHEMISTRY OF ALIPHATIC ORGANIC PEROXIDES, Applied spectroscopy, 51(1), 1997, pp. 74-80
Citations number
24
Categorie Soggetti
Instument & Instrumentation",Spectroscopy
Journal title
Applied spectroscopy → ACNP
ISSN journal
00037028
Volume
51
Issue
1
Year of publication
1997
Pages
74 - 80
Database
ISI
SICI code
0003-7028(1997)51:1<74:FSORAA>2.0.ZU;2-Y
Abstract
The described investigations are focused on peroxides occurring as pro ducts in atmospheric chemical processes, namely, hydrogen peroxide, me thylhydroperoxide, hydroxymethylhydroperoxide, bis-(hydroxymethyl)pero xide, 1-hydroxyethylhydroperoxide, bis-(hydroxyethyl)peroxide, and hyd roxymethylmethylperoxide. The compounds are identified and determined through the position and intensity of their characteristic O-O stretch ing bands in the range between 767 and 878 cm(-1), Time-resolved Raman spectroscopy of peroxide solutions permits the in situ investigation of pathways and kinetics of reactions between peroxides and aldehydes.