SIGMA-ASSISTANCE OF THE C-4-C-7 BOND IN THE SOLVOLYSIS OF 1-NORBORNYLTRIFLATES

Authors
MARTINEZ AG BARCINA JO HERRERO MER DEDIOS MI VILAR ET SUBRAMANIAN LR
Citation
Ag. Martinez et al., SIGMA-ASSISTANCE OF THE C-4-C-7 BOND IN THE SOLVOLYSIS OF 1-NORBORNYLTRIFLATES, Tetrahedron letters, 35(11), 1994, pp. 1793-1796
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
11
Year of publication
1994
Pages
1793 - 1796
Database
ISI
SICI code
0040-4039(1994)35:11<1793:SOTCBI>2.0.ZU;2-P
Abstract
The solvolysis of 4,7,7-trimethyl-1-norbornyl triflate (5) proceeds un der sigma-participation of the C-4-C-7 bond, with formation of the sig ma bridged cation 22 as intermediate.