Qy. Wu et al., NEW DISCOVERIES IN STUDY ON HYDROCARBONS FROM THERMAL-DEGRADATION OF HETEROTROPHICALLY YELLOWING ALGAE, Science in China. Series B, Chemistry, life sciences & earth sciences, 37(3), 1994, pp. 326-335
Green autotrophic alga Chlorella protothecoides contains a very small
quantity of hydrocarbons. Heterotrophic culture of this alga results i
n the cells yellowing, chlorophyll disappearing, protein decreasing an
d lipid increasing remarkably. The quantities of hydrocarbons from the
m directly and from the thermal degradation of the cells at or below 2
00-degrees-C are very low. These hydrocarbons are characterized by pre
dominance of high molecular weight normal alkanes with maximum at C23-
C25. When these heterotrophically yellowing cells are thermally degrad
ed at 300-degrees-C, the aliphatic hydrocarbons increase greatly, 32 t
imes that of the green autotrophic ones at the same temperature. Meanw
hile, the low molecular weight normal alkanes with C-17 as the peak be
come predominant instead of the original ones of high molecular weight
. The actual potential of microplanktonic algae in producing hydrocarb
ons should be much greater than what people have recognized before.