RAMAN STUDIES OF URANYL-NITRATE AND ITS HYDROXY BRIDGED DIMER

Authors
FAULQUES E RUSSO RE PERRY DL
Citation
E. Faulques et al., RAMAN STUDIES OF URANYL-NITRATE AND ITS HYDROXY BRIDGED DIMER, Spectrochimica acta. Part A: Molecular spectroscopy, 50(4), 1994, pp. 757-763
Citations number
17
Categorie Soggetti
Spectroscopy
Journal title
Spectrochimica acta. Part A: Molecular spectroscopy → ACNP
ISSN journal
05848539
Volume
50
Issue
4
Year of publication
1994
Pages
757 - 763
Database
ISI
SICI code
0584-8539(1994)50:4<757:RSOUAI>2.0.ZU;2-4
Abstract
In this paper, the authors report Raman spectra obtained on imidazoliu m di-mu-hydroxybis[dioxobis-(nitrato)uranium(VI)], (UO2(NO3)2(OH))2.2C 3H5N2 (IUNH). An assignment of the Raman bands is made by comparing th e spectrum of IUNH with those of uranyl nitrate hexahydrate (UNH) and imidazole (IMID). The electron charge transfer from the imidazole ring to the uranyl ion has been empirically determined.