We have studied uniaxially stressed Ge doped with Cu, a substitutional
triple acceptor, by photoconductivity spectroscopy. We find that the
ground state of this triple acceptor, normally accommodating three 1s
holes, reconfigures into an atomic Li-like 1s(2)2s1 arrangement by the
application of [100] stress. Above 4 kbar the first ionization potent
ial reaches a constant value of 17.4 meV corresponding to the hole exc
itation from the now partially occupied 2s energy level. Excellent agr
eement was obtained between the experimental results and variational c
alculations.