SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL BINUCLEAR COPPERCOMPLEX - IS[MU-O,O'-6-(2,2'-BIPYRIDYL)HEXALATO]DICOPPER(II) BIS(PERCHLORATE)

Authors
LIU BY GANZEL P TRAYLOR TG
Citation
By. Liu et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A NOVEL BINUCLEAR COPPERCOMPLEX - IS[MU-O,O'-6-(2,2'-BIPYRIDYL)HEXALATO]DICOPPER(II) BIS(PERCHLORATE), Inorganica Chimica Acta, 254(2), 1997, pp. 407-410
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
254
Issue
2
Year of publication
1997
Pages
407 - 410
Database
ISI
SICI code
0020-1693(1997)254:2<407:SASCOA>2.0.ZU;2-R
Abstract
A new tetradentate ligand 6-(2,2'-bipyridyl)hexanoic acid and its copp er(II) complex s[mu-O,O'-6-(2,2'-bipyridyl)hexalato]-dicopper(II) bis( perchlorate) have been synthesized and characterized. The structure of the latter is revealed by X-ray crystallography. Crystal data at 173 K: monoclinic space group C2/c, a = 12.744(4), b = 15.029(4), c = 18.9 56(5) Angstrom, beta = 108.29(2)degrees, V = 3447.1(16) Angstrom(3),Z = 4, R = 0.051, R(w) = 0.063.