PHOTOREACTIVITY OF HEMATOPORPHYRIN IX-DICHLOROPLATINUM(II) - LIGHT-INDUCED RELEASE AND ACTIVATION OF FREE-BASE HEMATOPORPHYRIN

Authors
KUNKELY H VOGLER A
Citation
H. Kunkely et A. Vogler, PHOTOREACTIVITY OF HEMATOPORPHYRIN IX-DICHLOROPLATINUM(II) - LIGHT-INDUCED RELEASE AND ACTIVATION OF FREE-BASE HEMATOPORPHYRIN, Inorganica Chimica Acta, 254(2), 1997, pp. 417-419
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
254
Issue
2
Year of publication
1997
Pages
417 - 419
Database
ISI
SICI code
0020-1693(1997)254:2<417:POHI-L>2.0.ZU;2-7
Abstract
The complex Pt(II) (hematoporphyrinH(2))Cl-2 which contains free base porphyrin as a bidentate ligand is light sensitive. In DMF a photosubs titution takes place. The porphyrin is released with phi similar to 2 X 10(-3) at lambda(irr) = 405 nm. It is assumed that the photolysis or iginates from a ligand field state which is populated from pi pi intr aligand states. In a secondary photolysis the porphyrin undergoes a de composition in agreement with previous results.