INFLUENCE OF POTASSIUM-NITRATE ADDITION TO SILICA-SUPPORTED PD CATALYSTS ON CHEMISORPTION PROPERTIES AND ON ETHANE HYDROGENOLYSIS

Authors
MIKHAILENKO SD PITCHON V PRALIAUD H MARTIN GA
Citation
Sd. Mikhailenko et al., INFLUENCE OF POTASSIUM-NITRATE ADDITION TO SILICA-SUPPORTED PD CATALYSTS ON CHEMISORPTION PROPERTIES AND ON ETHANE HYDROGENOLYSIS, Reaction kinetics and catalysis letters, 51(2), 1993, pp. 261-267
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
51
Issue
2
Year of publication
1993
Pages
261 - 267
Database
ISI
SICI code
0133-1736(1993)51:2<261:IOPATS>2.0.ZU;2-F
Abstract
KNO3 addition to Pd/SiO2 results in a partial decoration of metal part icles which inhibits ethane adsorption. Hydrogen chemisorption is less affected. The rate of ethane hydrogenolysis decreases and the activat ion energy increases.