MONTE-CARLO STUDIES OF TRIGGER SELF-OSCILLATIONS IN A BIMOLECULAR HETEROGENEOUS CATALYTIC REACTION

Authors
LUTSEVICH LV ELOKHIN VI YABLONSKII GS
Citation
Lv. Lutsevich et al., MONTE-CARLO STUDIES OF TRIGGER SELF-OSCILLATIONS IN A BIMOLECULAR HETEROGENEOUS CATALYTIC REACTION, Reaction kinetics and catalysis letters, 51(2), 1993, pp. 269-277
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
51
Issue
2
Year of publication
1993
Pages
269 - 277
Database
ISI
SICI code
0133-1736(1993)51:2<269:MSOTSI>2.0.ZU;2-3
Abstract
Dynamics of processes on metal surfaces and conditions for rate oscill ations taking into account reconstruction of the catalyst are investig ated using the Monte-Carlo method for a catalytic reaction following t he Langmuir-Hinshelwood mechanism. Different regions of the oscillatio ns were found particularly the region where the oscillations are gover ned by the formation of a steady compact cluster which controls the fr equency and amplitude of oscillations.