NMR CONFORMATIONAL-ANALYSIS OF COMPLEXES OF THE CARBOXYLIC IONOPHORE NIGERICIN WITH NA+ AND K+

Authors
BELOEIL JC BIOU V DAUPHIN G GARNIER J MORELLET N VAUFREY F
Citation
Jc. Beloeil et al., NMR CONFORMATIONAL-ANALYSIS OF COMPLEXES OF THE CARBOXYLIC IONOPHORE NIGERICIN WITH NA+ AND K+, Magnetic resonance in chemistry, 32(2), 1994, pp. 83-86
Citations number
31
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
32
Issue
2
Year of publication
1994
Pages
83 - 86
Database
ISI
SICI code
0749-1581(1994)32:2<83:NCOCOT>2.0.ZU;2-Q
Abstract
The conformations of the complexes formed by the ionophore nigericin w ith Na+ and K+ in CDCl3 solution determined by ROESY NMR and distance geometry computations are in good agreement with the X-ray crystallogr aphic data. The structures with the Na+ ion are more compact than thos e with the K+ ion, as the latter have a wider cage for the ion.