STRUCTURAL STUDIES ON CHIRAL (PI-ALLYL)PD(II) COMPLEXES - H-1, C-13 AND P-31 NMR-STUDIES OF [PD(ETA(3)-CH3CHCHCH2)(S, S-CHIRAPHOS)]CF3SO3

Authors
PREGOSIN PS SALZMANN R
Citation
Ps. Pregosin et R. Salzmann, STRUCTURAL STUDIES ON CHIRAL (PI-ALLYL)PD(II) COMPLEXES - H-1, C-13 AND P-31 NMR-STUDIES OF [PD(ETA(3)-CH3CHCHCH2)(S, S-CHIRAPHOS)]CF3SO3, Magnetic resonance in chemistry, 32(2), 1994, pp. 128-133
Citations number
31
Categorie Soggetti
Spectroscopy,Chemistry
Journal title
Magnetic resonance in chemistry → ACNP
ISSN journal
07491581
Volume
32
Issue
2
Year of publication
1994
Pages
128 - 133
Database
ISI
SICI code
0749-1581(1994)32:2<128:SSOC(C>2.0.ZU;2-T
Abstract
The chiral (pi-allyl)Pd(II) complex [Pd(eta3-CH3CHCHCH2)(S, S-Chirapho s)]CF3SO3, was shown to exist in four isomeric forms (two diastereomer ic and two geometric). Aspects of their three-dimensional structures w ere elucidated using H-1, C-13 and P-31 one- and two-dimensional NMR m ethods. The assignment of the diastereomers, which differ with respect to the coordinated face of the allyl ligand, was achieved using H-1-N OESY methods.