The present paper discusses the synthesis of diamond in its metastable
region from carbonaceous gases, in particular methane. The diamond sy
nthesis on seed crystals is made possible owing to the orientation eff
ect of surface forces on the formation of a new phase. Discussed is al
so the joint crystallization of diamond and graphite. The basic experi
ments were made on highly dispersed diamond powders. The growth of dia
mond in kinetic and diffusion regions has been studied. Presented are
results of studying the fractionation of stable carbon isotopes when g
rowing a diamond.