Bv. Derjaguin et al., ON THE MECHANISM OF THE EMISSION OF HIGH-ENERGY ELECTRONS FROM THE SURFACES OF FRESHLY PEELED FILMS - POLYTETRAFLUOROETHYLENE, Progress in Surface Science, 45(1-4), 1994, pp. 168-174
This paper describes the results of an investigation of high-electron
emission accompanying the mechanical disruption of adhesive contact in
vacuo. Investigations of such emission parameters as the energy of th
e electrons, their angular distribution, depth of the electron capture
center levels on freshly formed polymer surfaces responsible for the
emission as well as the establishment of relations governing the time
variation of the parameters of the emitted electrons' flux, their rela
tion to the polymer film surface charge, and finally the numerical com
putations based on these experiments have led the authors to the concl
usion that the mechanism of electron emission from freshly formed poly
mer film surfaces has a field-emission nature proceeding from surface
states and is described accurately enough by the analytical expression
s derived from the above considerations.