Mf. Roden et al., NEW HE, ND, PB, AND SR ISOTOPIC CONSTRAINTS ON THE CONSTITUTION OF THE HAWAIIAN PLUME - RESULTS FROM KOOLAU VOLCANO, OAHU, HAWAII, USA, Geochimica et cosmochimica acta, 58(5), 1994, pp. 1431-1440
Most analyzed tholeiitic basalts from Koolau Volcano. Oahu, USA, have
strontium (Sr-87/Sr-86 = 0.7040-0.7043), neodymium (Nd-143/Nd-144 0.51
270-0.51276), and lead (Pb-206/Pb-204 = 17.8-17.9) isotopic compositio
ns near that of the bulk silicate earth, and He-3/He-4 isotopic ratios
of 11-14 times the atmospheric ratio. These helium ratios are higher
than MORB, but lower than those of lavas from Loihi seamount. Moreover
, the source for the Koolau tholeiites is inferred to have non-bulk ea
rth abundance ratios of highly incompatible elements. Consequently, th
e source of the Koolau lavas is not primitive, undegassed mantle. The
abundance ratios La/Nb, Zr/Nb, and Sr/Nb correlate with Sr-87/Sr-86 an
d Nd-143/Nd-144 ratios in Hawaiian tholeiites. The enriched (Koolau) s
ource component has relatively high La/Nb, Zr/Nb, and Sr/Nb ratios; in
fact, Koolau tholeiites have higher Zr/Nb and La/Nb, and lower Th/Nb
than most other OIB. These combined trace element and isotopic signatu
res of the enriched component are not consistent with derivation from
primitive mantle, recycled crustal material, or a carbonatite metasoma
tized source. A simple explanation is that the enriched component is r
esidual material, formed recently when a small amount of melt was extr
acted from primitive mantle, perhaps during the incorporation of the K
oolau component into the plume.