INTERACTION OF THE LYSINE SIDE-CHAIN AMINO GROUP WITH CUII IN (GLYCYL-L-LYSINE2-)CU

Authors
FUSCH G HILLGERIS EC LIPPERT B
Citation
G. Fusch et al., INTERACTION OF THE LYSINE SIDE-CHAIN AMINO GROUP WITH CUII IN (GLYCYL-L-LYSINE2-)CU, Inorganica Chimica Acta, 217(1-2), 1994, pp. 33-38
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
217
Issue
1-2
Year of publication
1994
Pages
33 - 38
Database
ISI
SICI code
0020-1693(1994)217:1-2<33:IOTLSA>2.0.ZU;2-G
Abstract
Two different modifications of the (gly-L-lys2-)Cu(II) complex (1 and 2) were determined by X-ray crystallography. The dipeptide forms a tri dentate chelate via COO- (lysine), NH2 (glycine) and the deprotonated amide group. The amino group of the lysine side chain links copper uni ts, thereby generating a one-dimensional polymeric structure. The two modifications differ in a coordinated water molecule at the Cu(II) wit h 1 analyzing as (C8H15N3O3)Cu(H2O) and 2 as (C8H15N3O3)Cu.2H2O.