L. Shang et al., THE DEVELOPMENT OF AN ANISOTROPIC SI ETCH PROCESS SELECTIVE TO GEXSI1-X UNDERLAYERS, Journal of the Electrochemical Society, 141(2), 1994, pp. 507-510
In this paper we present the development of a technique for anisotropi
cally etching silicon on GeSi. Wet chemical etching exhibits a selecti
vity of nearly 40:1 but is completely isotropic and requires the use o
f a hard mask. The fluorine plasma process which has been reported in
the literature as having high selectivity was nonreproducible as a res
ult of significant polymeric deposition the chamber surfaces. Furtherm
ore the etch residue was not easily removed in an O2 plasma and led to
highly resistive contacts. Reactive ion etch processes using BCl3/Cl2
and SiCl4 were found to anisotropically etch the silicon layer, had p
oor selectively to GeSi. By combining a reactive ion etch at 300 W for
ward power and 20 mTorr in SiCl4, with a wet chemical dip, an adequate
process for selectively patterning submicron features was obtained.