V. Svorcik et al., MODIFICATION OF POLYETHYLENETEREPHTHALATE BY IMPLANTATION OF NITROGEN-IONS, Journal of the Electrochemical Society, 141(2), 1994, pp. 582-584
The implantation of 90 keV N+ ions into polyethyleneterephtalate (PET)
to fluences of 1 X 10(14)-1 X 10(17) cm-2 was studied. The changes in
electrical sheet conductivity and polarity of ion-exposed PET were ob
served and the structural changes were examined using IR spectroscopy.
One degradation process is a chain fission according to the Norrish I
I reaction. The sheet conductivity due to conjugated double bonds was
increased by ten orders of magnitude as a result of ion implantation.
The surface polarity of the PET samples increases slightly with increa
sing ion fluence.