X-ray photoelectron spectroscopy (XPS), combined with scanning electro
n microscopy (SEM), weight loss tests and atomic absorption spectrosco
py (AAS), has been applied to investigate the corrosion protection pro
perties of zinc phosphate when coated on 7075-T6 aluminium alloy. XPS
is consistent with the coating process leading to both physically adso
rbed and chemically absorbed zinc. The former is washed away by ultras
onic washing, but the chemically absorbed component, identified as ZnO
(x), is incorporated into the aluminium oxide layer. This layer helps
suppress the dissolution of aluminium during the corrosion process.