AN UNPRECEDENTED RUTHENIUM ALLENYLIDENE COMPLEX CONTAINING AN UNSATURATED BICYCLIC SYSTEM - FORMAL ADDITION OF 1-ETHYNYL-1-CYCLOHEXANOL TO AN ALKENYLVINYLIDENE INTERMEDIATE COMPLEX

Authors
CADIERNO V GAMASA MP GIMENO J LASTRA E BORGE J GARCIAGRANDA S
Citation
V. Cadierno et al., AN UNPRECEDENTED RUTHENIUM ALLENYLIDENE COMPLEX CONTAINING AN UNSATURATED BICYCLIC SYSTEM - FORMAL ADDITION OF 1-ETHYNYL-1-CYCLOHEXANOL TO AN ALKENYLVINYLIDENE INTERMEDIATE COMPLEX, Organometallics, 13(3), 1994, pp. 745-747
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
13
Issue
3
Year of publication
1994
Pages
745 - 747
Database
ISI
SICI code
0276-7333(1994)13:3<745:AURACC>2.0.ZU;2-7
Abstract
The stoichiometric activation of 1-ethynyl-1-cyclohexanol by [RuCl(PPh 3)2(eta-C9H7)] in the presence of NaPF6 allows the formation of the pr opadienylidene ruthenium complex 1, containing a new spirobicyclic sys tem which is formed through an unprecedented coupling process. The cry stal structure of 1 has been determined by X-ray diffraction crystallo graphy.