Kk. Ko et Sw. Pang, SURFACE DAMAGE ON GAAS ETCHED USING A MULTIPOLAR ELECTRON-CYCLOTRON-RESONANCE SOURCE, Journal of the Electrochemical Society, 141(1), 1994, pp. 255-258
Surface damage on GaAs induced by etching using an electron cyclotron
resonance (ECR) source has been studied as a function of pressure, mic
rowave power, sample distance from the ECR source, RF power, and gas c
omposition. Damage was evaluated by measuring the current-voltage (I-V
) and capacitance-voltage (C- V) characteristics on Schottky diodes fa
bricated on the etched surface. Etch-induced damage is found to depend
mainly on the ion energy and the concentration of reactive species. T
he diode characteristics are improved when the samples are etched at l
ower pressure, higher microwave power, and closer distance to the ECR
source. The diodes become more leaky and the intercept voltage extract
ed from the C-V measurements increased at higher RF power, which sugge
sts the formation of a heavily damaged layer at higher ion energy. It
is also found that an Ar plasma introduces more damage than a N2 plasm
a as observed by a higher ideality factor and a lower barrier height o
n the samples etched by Ar sputtering. Addition of Cl2, as little as 1
0%, results in diode characteristics close to that of the unetched sam
ple. The damage observed can be classified into major and minor degree
s of damage. In this study, most of the samples have only minor damage
. Major damage was observed only on samples that were etchecl at high
RF power or with a low concentration of reactive species.