SYNTHESIS AND CRYSTAL-STRUCTURE OF [NA(12 -CROWN-4)(2)](2)[FE4SE4CL4]

Authors
AHLE A DEHNICKE K MAICHLEMOSSMER C STRAHLE J
Citation
A. Ahle et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF [NA(12 -CROWN-4)(2)](2)[FE4SE4CL4], Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 49(3), 1994, pp. 434-436
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
49
Issue
3
Year of publication
1994
Pages
434 - 436
Database
ISI
SICI code
0932-0776(1994)49:3<434:SACO[->2.0.ZU;2-P
Abstract
[Na(12-crown-4)(2)]2Fe4Se4Cl4] has been prepared by the reaction of Fe Cl2 with Na2Se4 in dimethylformamide solution in the presence of 12-cr own-4 as dark red crystals, which were characterized by a crystal stru cture determination. Space group P ($) over bar 1, Z = 2, 6295 observe d unique reflections, R = 0.085. Lattice dimensions at 20 degrees C: a = 1397.3(3), b = 1501.8(4), c = 1570.1(4) pm, alpha = 85.86(2)degrees , beta = 64.06(2)3, gamma = 65.01(2)degrees. The structure consists of [Na(12-crown-4)(2)](+) cations and cuban-like anions [Fe4Se4Cl4](2-) with Fe...Fe contacts of282.8(3) pm.