C. Lamberti et al., EXTENDED X-RAY-ABSORPTION FINE-STRUCTURE INVESTIGATION ON BURIED INASP INP INTERFACES/, Applied physics letters, 64(11), 1994, pp. 1430-1432
As K-edge extended x-ray absorption fine structure has been carried ou
t on the 2-3 monolayers thick interface of ad hoc grown InAsP/InP expi
taxial multistructures deposited by low pressure metalorganic vapor ph
ase epitaxy. The goal was to characterize the local structure of the u
nwanted, strained interface layers of InAsP produced by the exposure o
f the InP surface to AsH3 as occurs during the growth of InP/InGaAs he
terostructures. We observed that the first shell environment of As at
these interfaces is identical to that found in bulk InAs. In particula
r, we measure a constant As-In bond length, independently of As concen
tration at the interface; this implies that epitaxy with InP is accomp
anied by local structural distortions which accommodate the constant A
s-In bond length.