THE GAS-PHASE STRUCTURES OF CF3NBR2 AND ( CF3)2NBR

Authors
MINKWITZ R LAMEK D OBERHAMMER H MACK HG
Citation
R. Minkwitz et al., THE GAS-PHASE STRUCTURES OF CF3NBR2 AND ( CF3)2NBR, Zeitschrift fur anorganische und allgemeine Chemie, 620(2), 1994, pp. 353-356
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur anorganische und allgemeine Chemie
ISSN journal
00442313 → ACNP
Volume
620
Issue
2
Year of publication
1994
Pages
353 - 356
Database
ISI
SICI code
0044-2313(1994)620:2<353:TGSOCA>2.0.ZU;2-T
Abstract
The gas phase structures of the trifluoromethyl bromoamines CF3NBr2 an d (CF3)2NBr were determined by electron diffraction. CF3NBr2: N-Br = 1 88.0(3), N-C = 148.1(13) pm, BrNBr = 11 1.1(6)-degrees and BrNC = 107. 3(8)-degrees; (CF3)2NBr: N-Br = 186.9(4), N-C = 144.9(7) pm, BrNC = 11 4.9(9)-degrees and CNC = 118.6(24)-degrees. The results for these brom oamines are compared to those for the analogous fluoro and chloroamine s.