Very low mass stars and brown dwarfs have low effective temperatures a
nd their atmospheric opacities are provided by heavy elements which fo
rm a host of strongly absorbing molecules. We present a study of the a
tmospheres and emergent spectra of these objects in the limiting case
of zero metallicity. A grid of atmosphere models is presented, based o
n updated opacities for H/He mixtures, in particular for the collision
-induced absorption by H-2 which plays an important role in these atmo
spheres. The emergent spectra bear little resemblance to the correspon
ding blackbody emission and become bluer as the effective temperature
is lowered. The atmosphere models are coupled with interior calculatio
ns to obtain accurate physical and photometric characteristics for the
low-mass end of the zero-metallicity main sequence. This provides a u
seful boundary in the Hertzsprung Russel diagram to interpret observat
ions of low-metallicity stars.