PALLADIUM-CATALYZED VINYLATION OF TERTIARY ALLYLIC ALCOHOLS - A NEW PROTOCOL FOR THE SYNTHESIS OF ISOPRENOID ALDEHYDES

Authors
BIENAYME H YEZEGUELIAN C
Citation
H. Bienayme et C. Yezeguelian, PALLADIUM-CATALYZED VINYLATION OF TERTIARY ALLYLIC ALCOHOLS - A NEW PROTOCOL FOR THE SYNTHESIS OF ISOPRENOID ALDEHYDES, Tetrahedron, 50(11), 1994, pp. 3389-3396
Citations number
67
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
11
Year of publication
1994
Pages
3389 - 3396
Database
ISI
SICI code
0040-4020(1994)50:11<3389:PVOTAA>2.0.ZU;2-T
Abstract
Heck vinylation of tertiary allylic alcohols with iodo-acetal Ic, foll owed by an acid catalysed acetal hydrolysis-dehydration reaction, furn ished isoprenoid aldehydes regioselectively in high yields