Y. Umemura et al., MOSSBAUER STUDY ON TRIS (1, 10-PHENANTHROLINE) IRON (II) ION SYNTHESIZED IN ZEOLITE-Y AND ITS PYROLYSIS PRODUCTS, Journal of radioanalytical and nuclear chemistry, 186(3), 1994, pp. 213-226
Tris(1,10-phenanthroline)iron(II) ([Fe(phen)3]2+) ion synthesized in t
he supercage of zeolite Y has been characterized by Mossbauer, UV-VIS
reflectance, and X-ray diffraction methods. The complex in the superca
ge may be significantly distorted by interaction between the complex A
nd the supercage wall. Pyrolysig mechanism under air of the complex in
the supercage was studied on the basis of Mossbauer spectra.