SEPARATION OF METAL-CYANIDE COMPLEXES BY REVERSED-PHASE ION-INTERACTION HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY

Reversed-phase ion-interaction chromatography has been used to study t he separation of Cu(I), Ag(I), Ni(II), Au(I), Co(III), Fe(III), and Fe (II) cyano complexes on silica and carbon-based reversed-phases with U V detection at 215 nm. Separation of the metal-cyanide complexes was a ffected by a number of experimental factors including the nature and c oncentration of the organic modifier, nature and concentration of the ion-pairing reagent, pH, and ionic strength of the mobile phase. Diffe rences between the elution order of metallo-cyanides observed in the p resent work and in other investigations under similar experimental con ditions are explained by a difference in the ionic strength of the mob ile phase. Finally, this technique is used to analyze metal-cyanide co mplexes in a gold mill solution.