SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF POLY(DIHALOPHENYLENE-OXIDE)S BASED ON THE THERMAL-DECOMPOSITION OF BIS(4-CHLORO-2-6-DIBROMOPHENOXO) ETHYLENEDIAMINE COPPER(II) COMPLEX IN TOLUENE

Authors
PULAT M SANLL O KISAKUREK D
Citation
M. Pulat et al., SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF POLY(DIHALOPHENYLENE-OXIDE)S BASED ON THE THERMAL-DECOMPOSITION OF BIS(4-CHLORO-2-6-DIBROMOPHENOXO) ETHYLENEDIAMINE COPPER(II) COMPLEX IN TOLUENE, Polish Journal of Chemistry, 68(3), 1994, pp. 453-458
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
68
Issue
3
Year of publication
1994
Pages
453 - 458
Database
ISI
SICI code
0137-5083(1994)68:3<453:SASCOP>2.0.ZU;2-8
Abstract
Synthesis of poly (dihaloplienylene oxides) by thermal decomposition o f bis (4-chloro-2,6-dibromoplienoxo) ethylenediamine copper (II) compl ex was achieved in toluene at 70-degrees-C. The structural characteriz ation of polymer were carried out by FTIR, H-1-NMR and C-13-NMR spectr oscopies and differential scanning calorimetry. It was found that 4-ch loro-2,6-dibromophenoxide with chelating ligand, ethylenediamine, disp layed a selectivity in favour of 1,2- catenation.