CHIRAL SYNTHONS FROM CARVONE .24. PHOTOCHEMICAL REARRANGEMENTS OF CHIRAL BICYCLO[2.2.2]OCT-5-EN-2-ONES

Authors
SRIKRISHNA A DANIELDOSS S
Citation
A. Srikrishna et S. Danieldoss, CHIRAL SYNTHONS FROM CARVONE .24. PHOTOCHEMICAL REARRANGEMENTS OF CHIRAL BICYCLO[2.2.2]OCT-5-EN-2-ONES, Synthetic communications, 27(4), 1997, pp. 655-661
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
27
Issue
4
Year of publication
1997
Pages
655 - 661
Database
ISI
SICI code
0039-7911(1997)27:4<655:CSFC.P>2.0.ZU;2-C
Abstract
Photochemical oxadi-pi-methane rearrangement (1,2-acyl shift) of the c hiral bicyclo[2.2.2]oct-5-en-2-ones 2 and 3 furnishes the tricyclic ke tones 5 and 6, whereas the 1,3-acyl shift generates the cyclobutanones 7 and 8 respectively.