GaN single. crystals were prepared in a sealed stainless steel tube at
600-800 degrees C from Ga using a Na flux and N-2 from the thermal de
composition of sodium azide, NaN3. The maximum size of the crystals ob
tained was 2 mm. Oxygen and other impurity elements were not detected
in the crystals by AES and EDX. When scaled up, this method may provid
e large GaN crystals for use as substrates for nitride based lasers.