R. Pinto et al., OXYGEN ORDER, STRUCTURE AND SUPERCONDUCTIVITY IN YBA2CU3O7-DELTA FILMS DURING IN-SITU FORMATION, Superconductor science and technology, 7(3), 1994, pp. 95-98
We have studied the structure and oxygen incorporation in YBa2Cu3O7-de
lta thin films during in situ formation by pulsed laser deposition. A
quenching technique has been used for the first time to freeze the nat
ure of in situ films immediately on termination of growth. In situ res
istance and transition-temperature measurements, and x-ray diffraction
studies on undoped and Ag-doped films, have shown that an oxygen-defi
cient orthorhombic phase is indeed possible during growth due to the p
resence of atomic and ionized oxygen species in the laser-induced plas
ma.