LOCAL COMPOSITION OF SILICON OXYCARBIDES OBTAINED BY LASER SPRAY-PYROLYSIS

New nanosized Si/O/C composites have been synthesized by laser-aerosol interaction. The Si-29 spectra revealed a deep rearrangement of Si bo nding in the samples with respect to the original aerosol. From the si loxane (CH3)(3)SiOSi(CH3)(3) (MDSO) and the silane C2H5OSi(CH3)(3) (ET MS) aerosols with M environments, solids with a wide variety of SiOxC4 -x environments were produced. These environments were shown to be ran domly distributed. On the other hand, the same Q environment from the Si(OC2H5)(4) (TEOS) aerosol remained in the powders. This can be ratio nalized in terms of Si-O and Si-C bond exchanges. After pyrolysis and before crystallization, there was a clear deviation from the random mo del indicating that the material started to organize. C-13 and H-1 NMR distinguished Si-C and aromatic free C. Both spectroscopies indicated that there was less C in the Si/O/C phase of the ex-MDSO powder than in the ex-ETMS one. The ex-MDSO Si/O/C was therefore less oxygenated, contained less carbon,and consequently the most condensed of the two. This study illustrates the great versatility of the method. The local environment of the Si in the precursor is modified through a limited b ond redistribution and condensation during the synthesis and before py rolysis. The choice of a Q organosilane, not allowing bond redistribut ion, leads to a highly porous, nanosized silica, because excess aromat ic carbon is burned off by thermal oxidation. On the other hand, a cho ice of a precursor with a mixed SiOxC4-x environment leads after pyrol ysis under an inert atmosphere to a mixture of Sii O/C and free aromat ic carbon.