THE TORGOV REACTION AS A SHORT-CUT TO KAMETANI SYNTHESIS OF (PLUS-OR-MINUS)14-ALPHA-HYDROXYESTRONE AND DERIVATIVES

Authors
BLAZEJEWSKI JC HADDAD M WAKSELMAN C
Citation
Jc. Blazejewski et al., THE TORGOV REACTION AS A SHORT-CUT TO KAMETANI SYNTHESIS OF (PLUS-OR-MINUS)14-ALPHA-HYDROXYESTRONE AND DERIVATIVES, Tetrahedron letters, 35(13), 1994, pp. 2021-2022
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
35
Issue
13
Year of publication
1994
Pages
2021 - 2022
Database
ISI
SICI code
0040-4039(1994)35:13<2021:TTRAAS>2.0.ZU;2-9
Abstract
A key intermediate in Kametani's synthesis of 14alpha-hydroxyestrone i s prepared in two steps via a Torgov like reaction of 2-methylcyclopen tane-1,3-dione with a vinylbenzocyclobutenyl alcohol.