THERMOPHYSICAL PROPERTIES OF ALKALI-METAL VAPORS .2. ASSESSMENT OF EXPERIMENTAL-DATA ON THERMAL-CONDUCTIVITY AND VISCOSITY

Citation
Ps. Fialho et al., THERMOPHYSICAL PROPERTIES OF ALKALI-METAL VAPORS .2. ASSESSMENT OF EXPERIMENTAL-DATA ON THERMAL-CONDUCTIVITY AND VISCOSITY, Berichte der Bunsengesellschaft fur Physikalische Chemie, 98(1), 1994, pp. 92-102
Citations number
29
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
ISSN journal
00059021 → ACNP
Volume
98
Issue
1
Year of publication
1994
Pages
92 - 102
Database
ISI
SICI code
0005-9021(1994)98:1<92:TPOAV.>2.0.ZU;2-9
Abstract
An analysis of the available data on the viscosity and thermal conduct ivity coefficients of the alkali metal vapours is presented. The analy sis is based upon theoretical calculations of the properties of the mo natomic systems, described in the preceeding parts I and I.A of the pr esent paper, and making use of the kinetic theory of a binary gas reac ting mixture. A summary of the measurement techniques used, including, whenever possible, the magnitude of the corrections performed on the raw data and the nominal precision of the results, complements the ana lysis. It is concluded that it is possible to select precise and mutua lly consistent sets of experimental results for both viscosity and the rmal conductivity coefficients of lithium, sodium and potassium vapour s among the available literature data and to classify all the data in uncertainty classes. Regarding rubidium and cesium no systematic discu ssion is possible due to a lack of experimental data with sufficient p recision.