ALKYLATION IN ELECTRON-IMPACT MASS-SPECTROMETRY OF HYDROBROMIDES OF 2-ALKYLTHIOOROTIC ACIDS

Authors
WYRZYKIEWICZ E BARTKOWIAK G
Citation
E. Wyrzykiewicz et G. Bartkowiak, ALKYLATION IN ELECTRON-IMPACT MASS-SPECTROMETRY OF HYDROBROMIDES OF 2-ALKYLTHIOOROTIC ACIDS, Organic mass spectrometry, 29(1), 1994, pp. 50-54
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear",Spectroscopy
Journal title
Organic mass spectrometry → ACNP
ISSN journal
0030493X
Volume
29
Issue
1
Year of publication
1994
Pages
50 - 54
Database
ISI
SICI code
0030-493X(1994)29:1<50:AIEMOH>2.0.ZU;2-J
Abstract
The mass spectral fragmentations of eight 2-alkylthioorotic acids and their hydrobromides were investigated. Fragmentation pathways, the elu cidation of which was assisted by accurate mass measurements and metas table transitions, are proposed. It was found that there is evidence i n the electron impact mass spectra of the hydrobromides of 2-alkylthio orotic acids of intermolecular transfer of an alkyl group.