BOVINE LIVER ACETONE POWDER (BLAP) CATALYZED SYNTHESIS OF CHIRAL C-8 ALLYL ALCOHOLS - AN APPLICATION OF SUBSTRATE-SPECIFICITY APPROACH

Authors
BASAVAIAH D RAJU SB
Citation
D. Basavaiah et Sb. Raju, BOVINE LIVER ACETONE POWDER (BLAP) CATALYZED SYNTHESIS OF CHIRAL C-8 ALLYL ALCOHOLS - AN APPLICATION OF SUBSTRATE-SPECIFICITY APPROACH, Tetrahedron, 50(14), 1994, pp. 4137-4148
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
50
Issue
14
Year of publication
1994
Pages
4137 - 4148
Database
ISI
SICI code
0040-4020(1994)50:14<4137:BLAP(C>2.0.ZU;2-0
Abstract
(S)-Matsutake alcohol is synthesized by enzymatic hydrolysis in 92% op tical purity using bovine liver acetone powder (BLAP). The principle o f substrate specificity approach is applied to the synthesis of C-8 al lyl alcohols in 46-93% enantiomeric purities using BLAP.