SYNTHESES AND CRYSTAL-STRUCTURES OF CUPRATE COMPLEXES OF EUROPIUM ANDYTTERBIUM, ([(PHC-C)(3)CU][EU(PY)(THF)(2)])(2) AND ([(PHC-C)(3)CU][YB(THF)(2)])(2)

Authors
BOCHKAREV LN DRUZHKOVA ON ZHILTSOV SF ZAKHAROV LN FUKIN GK KHORSHEV SY YANOVSKY AI STRUCHKOV YT
Citation
Ln. Bochkarev et al., SYNTHESES AND CRYSTAL-STRUCTURES OF CUPRATE COMPLEXES OF EUROPIUM ANDYTTERBIUM, ([(PHC-C)(3)CU][EU(PY)(THF)(2)])(2) AND ([(PHC-C)(3)CU][YB(THF)(2)])(2), Organometallics, 16(4), 1997, pp. 500-502
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
4
Year of publication
1997
Pages
500 - 502
Database
ISI
SICI code
0276-7333(1997)16:4<500:SACOCC>2.0.ZU;2-S
Abstract
The (Phenylethynyl)cuprate europium complex: {[(PhC=C)(3)Cu][Eu(Py)(TH F)(2)]}(2) (1) was synthesized by reaction of Eu with PhC=CCu in pyrid ine. The cuprate ytterbium complex {[(PhC=C)(3)Cu][Yb(THF)(2)]}(2) (2) was synthesized by reaction of Yb with PhC=CCu in THF in the presence of a catalytic amount of ytterbium diiodide and also by the reaction of(PhC=C)(2)Yb with PhC=CCu.