TRIS[(DIMETHYLAMINO)DIMETHYLSILYL]METHYL)MAGNESIUM IODIDE - A GRIGNARD-REAGENT WITHOUT A CARBON-MAGNESIUM BOND

Authors
EABORN C FAROOK A HITCHCOCK PB SMITH JD
Citation
C. Eaborn et al., TRIS[(DIMETHYLAMINO)DIMETHYLSILYL]METHYL)MAGNESIUM IODIDE - A GRIGNARD-REAGENT WITHOUT A CARBON-MAGNESIUM BOND, Organometallics, 16(4), 1997, pp. 503-504
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
4
Year of publication
1997
Pages
503 - 504
Database
ISI
SICI code
0276-7333(1997)16:4<503:TI-AG>2.0.ZU;2-2
Abstract
Reaction of (Me(2)NMe(2)Si)(3)CI with Mg gives the Grignard reagent (M e(2)NMe(2)Si)(3)CMgI, in which all three N atoms are coordinated to Mg and there is a planar carbanionic center, suggesting the absence of C ... Mg bonding.