Photoexcitation of pure C60 thin films by picosecond absorption spectr
oscopy reveals a transient species with absorption maxima at 540 nm an
d 660 nm which is assigned to the exciton. Considering the dynamic beh
aviour of this species and luminescence properties of solid C60, it is
concluded that a singlet exciton is observed both in its free (tau1/2
< 15 ps) and self-trapped (tau1/2 = 250 ns) forms.